A chemical oxygen generator is a device that releases oxygen created by a chemical reaction. The oxygen source is usually an inorganic superoxide, chlorate or perchlorate. A promising group of oxygen sources are ozonides. The generators are usually ignited mechanically, by a firing pin, and the chemical reaction is usually exothermic, making the generator a potential fire hazard. Potassium superoxide was used as an oxygen source on early manned USSR space missions, for firefighters and mine rescue.
Commercial aircraft provide emergency oxygen to passengers to protect them from drops in cabin pressure. Chemical oxygen generators are not used for the cockpit crew. For each row of seats there are overhead masks and oxygen generators. If a decompression occurs, the panels are opened either by an automatic pressure switch or by a manual switch, and the masks are released. When the passengers pull down on the mask they remove the retaining pins and trigger the production of oxygen.